ZLD Without Evaporation: Saltworks Achieves First ZLD With a Membrane Crystallizer

A Cost-Effective ZLD Solution for a Mining Client

September 2nd 2020

A New Kind of ZLD

Convention teaches that zero liquid discharge (ZLD) crystallizers require the energy-intensive boiling of water to produce solids. Our engineers recently broke that convention and helped a mining client achieve solid salt production in a novel membrane-chiller hybrid plant. The pilot project used ultra-high pressure reverse osmosis (UHP-RO) technology to replace a thermal evaporator; providing the client with an option for lower capital and operating costs over a conventional thermal ZLD option (which Saltworks also builds).

How did we do it?

Our engineers hybridized UHP-RO with a chilled crystallizer system, in a semi-closed loop that concentrates water, extracts solid salt, and repeats the cycle. The UHP-RO system can concentrate certain salts (e.g. sodium sulfate) to over 20% by mass. Examples of suitable ions include: Na+, K+, NH4+, CO32-, and SO42-. The concentrated brine solution then enters our chilled crystallizer, which takes advantage of steep solubility changes with temperature. There, the solution cools, resulting in the formation of salt crystals, which can be separated and removed. 

 

After cooling and salt extraction, the residual brine liquor has a lower dissolved salt content (~10%) and can be warmed up and recycled once again through the UHP-RO system. A heat pump is used to simultaneously cool one part of the circuit while heating the other — presenting considerable energy efficiency savings. As the loop operates, it continuously produces reverse osmosis quality permeate and solid salt crystals, while being replenished with make-up wastewater. No boiling means less energy consumed and lower costs.

chilled crystallizer salt
Sodium Sulfate: An Example of a Steep Solubility-Temperature Curve
CC_Salt-cropped-1
ZLD Without Evaporation: Solids Produced by our New ChilledCrys System

Contact Us With Specific Chemistry

The ChilledCrys membrane crystallizer system is not a silver bullet, suitable for all brines. However, for certain saltwater brines found in industry (e.g. sodium sulfate scrubber wastewaters), ChilledCrys can present considerable cost and energy savings. As with most things in water: it depends on the chemistry. Highly soluble ions will not crystallize through chilling, and organics or silica that accumulate require extraction. We have solutions and our engineers are ready to run detailed assessments for your water challenges. Contact us with your chemistry for an assessment. Find out if ChilledCrys can provide your project with the step change in ZLD costs that many are seeking.

About Saltworks

 

Saltworks Technologies is a leader in the development and delivery of solutions for industrial wastewater treatment and desalination. By working with customers to understand their unique challenges and focusing on continuous innovation, Saltworks’ solutions provide best-in-class performance and reliability on challenging waters. From its headquarters in Richmond, BC, Canada, Saltworks designs, builds, and operates full-scale treatment plants, and offers comprehensive offsite and onsite testing services with its fleet of mobile pilots.

Related Resources

chilledcrys chilled crystallizer pfd

SaltMaker ChilledCrys

Request More Information Learn More To produce solids, chilled crystallizers need to overcome a much lower thermodynamic barrier than evaporators. For very specific solution chemistries, chilled crystallization is a highly

More ...

Get Your Project Assessment

Get More Information on ChilledCrys Solutions & Products