RO & Evaporator Scale Control: The Guide to Better Performance

June 27th 2018

Scale is a crust that forms on membranes, heat transfer surfaces, and on the inside of pipes as salts precipitate out of solution. It blocks flow, disrupts heat transfer, and increases energy requirements for water treatment systems. Scale is bad news: it limits system performance and increases maintenance costs. You can protect your plant’s productivity from scale when you are armed with an understanding of scaling water chemistry and the right technology. You can also push and maximize performance of your plant, if you understand the scaling ‘danger zone’. Download our periodic table, which includes an easy to use guide and example. Keep reading to learn more. 

Periodic table of scaling compounds

How do Scaling Ions Precipitate?

Scaling occurs when ion pairs form salts as they reach their solubility limits. Ion pairs comprise positive cations and negative anions, and most scale is caused by ions that are multivalent pairs. Multivalent ions, such as calcium (Ca2+) and sulfate (SO42-), are more likely to cause scale than monovalent ions because they have lower solubilities and will precipitate earlier. Watch out, however, for one particular mono-multi pair, calcium (Ca2+) and fluoride (F), which can also cause scale. Our engineers use the above scaling periodic table of elements to easily check the concentrations where ions in water might precipitate and affect evaporator or membrane system performance.

 

The solubility of an individual ion pair is the most essential information to use when designing a scale management strategy. However, scaling concentration limits can be affected by the temperature, pH, and mixed-ion chemistry of the water. Ions in mixed solutions tend to have higher solubilities than pure solutions, which can be difficult to predict, even with some of the software models that are available. We treat mixed-ion effects as an extra buffer that prevents scale.

Photo of scaling found on the interior surface of pipes
Scaling found on the inside of pipes

How Does Scaling Impact Evaporators & Membrane Systems?

Any heat transfer surface where scaling occurs will observe decreased efficiency and capacity. Although scaling is typically shown on metal surfaces, it can also form on membranes used in reverse osmosis systems and reduce membrane performance. In severe cases, scale can mechanically damage or rupture the membrane.

 

A plant that ignores scaling limits can experience equipment plugging and surface crusting, or be operating sub-optimally for leaving room to increase freshwater recovery. Time and money are wasted on either low performance, or efforts to recover from a scaling event. Although carbonate scaling is easy to remove with acid, other scales take much more effort, such as using expensive chemical cleans or mechanical removal. It is best to know where you stand so that you can prevent scaling, rather than try to deal with it after it forms.

How to Avoid Scaling in Your Industrial Water Treatment Process

  • Get a complete analysis of your water chemistry to understand the concentrations of your potential scalant ions. For a few hundred dollars, you will receive analytical data that will help you understand low and high concentrations for your water. Ensure you sample during periods of both low and high concentration for a better representation of your complete picture.
  • Know the scaling potential of any scaling ions in your water by using our Periodic Table of Scaling Compounds, or find a software package if you wish to be more advanced.
  • Design and operate your process to push recovery, but avoid exceeding solubility limits of scaling ions.
  • Consider automated chemical softening that uses precision dosing to minimize the risk of scale formation, while also reducing wasted chemicals that may result from manual chemical softening.
  • Consider adding anti-scalants that may boost your scaling ion solubilities as much as 3–4x, but be sure to use the correct anti-scalant and consider testing. Many companies will sell you anti-scalants and their performance may vary.
  • Contact an expert at Saltworks today to optimize your process and prevent scale formation.

About Saltworks

Saltworks Technologies is a leader in the development and delivery of solutions for industrial wastewater treatment and lithium refining. By working with customers to understand their unique challenges and focusing on continuous innovation, Saltworks’ solutions provide best-in-class performance and reliability. From its headquarters in Richmond, BC, Canada, Saltworks designs, builds, and operates full-scale plants, and offers comprehensive offsite and onsite testing services with its fleet of mobile pilots.

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